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Potassium abundances in nearby metal-poor stars
Aims.The potassium abundances for 58 metal-poor stars are determinedusing high-resolution spectroscopy. The abundance trends in stars ofdifferent population are discussed. Methods: .All abundanceresults have been derived from NLTE statistical equilibrium calculationsand spectrum synthesis methods. Results: .The NLTE corrections aresignificant (-0.20 to -0.55 dex) and they depend on the effectivetemperatures and surface gravities. The potassium abundances of thindisk, thick disk and halo stars show distinct trends, such as in thecase of the α-elements. [K/Fe] gradually increases with a decreasein [Fe/H] for thin disk stars, [K/Fe] of thick disk stars is nearlyconstant at [K/Fe] ~ +0.30 dex; halo stars also have nearly constantvalues of [K/Fe] ~ +0.20 dex. Conclusions: .The deriveddependence between [K/Fe] and [Fe/H] is in agreement with thetheoretical prediction of published model calculations of the chemicalevolution of the Galaxy. The nearly constant [K/Mg] ratio with smallscatter suggests that the nucleosynthesis of potassium is closelycoupled to the α-elements.

Na, Mg and Al abundances as a population discriminant for nearby metal-poor stars
Aims.Parameters for 55 nearby metal-poor stars are determined usinghigh-resolution spectroscopy. Together with similar data taken from arecent analysis, they are used to show trends of their Galacticevolution with stellar [Fe/H] or [Mg/H] abundances. The separation ofabundance ratios between disk and halo stars is used as a basiccriterion for population membership. Methods.After carefulselection of a clean subsample free of suspected or known binaries andpeculiar stars, abundances of Mg, Na and Al are based on NLTE kineticequilibrium calculations applied to spectrum synthesis methods. Results.The relation between [Na/Mg] and [Fe/H] is a continuousenrichment through all three Galactic populations spanning a range ofvalues between a metal-poor plateau at [ Na/Mg] = -0.7 and solar values.[Al/Mg] displays a step-like difference between stars of the Galactichalo with overline[Al/Mg] ˜ -0.45 and the two disk populations withoverline[Al/Mg] ˜ +0.10. [Al/Mg] ratios, together with the [Mg/Fe]ratios, asymmetric drift velocities V, and stellar evolutionary ages,make possible the individual discrimination between stars of the thickdisk and the halo. At present, this evidence is limited by the smallnumber of stars, and by the theoretical and empirical uncertainties ofstellar age determinations, but it achieves a high significance. Conclusions.While the stellar sample is not complete with respect tospace volume, the resulting abundances indicate the necessity to revisecurrent models of chemical evolution to allow for an adequate productionof Al in early stellar generations.

Effective temperature scale and bolometric corrections from 2MASS photometry
We present a method to determine effective temperatures, angularsemi-diameters and bolometric corrections for population I and II FGKtype stars based on V and 2MASS IR photometry. Accurate calibration isaccomplished by using a sample of solar analogues, whose averagetemperature is assumed to be equal to the solar effective temperature of5777 K. By taking into account all possible sources of error we estimateassociated uncertainties to better than 1% in effective temperature andin the range 1.0-2.5% in angular semi-diameter for unreddened stars.Comparison of our new temperatures with other determinations extractedfrom the literature indicates, in general, remarkably good agreement.These results suggest that the effective temperaure scale of FGK starsis currently established with an accuracy better than 0.5%-1%. Theapplication of the method to a sample of 10 999 dwarfs in the Hipparcoscatalogue allows us to define temperature and bolometric correction (Kband) calibrations as a function of (V-K), [m/H] and log g. Bolometriccorrections in the V and K bands as a function of T_eff, [m/H] and log gare also given. We provide effective temperatures, angularsemi-diameters, radii and bolometric corrections in the V and K bandsfor the 10 999 FGK stars in our sample with the correspondinguncertainties.

Sulphur abundance in Galactic stars
We investigate sulphur abundance in 74 Galactic stars by using highresolution spectra obtained at ESO VLT and NTT telescopes. For the firsttime the abundances are derived, where possible, from three opticalmultiplets: Mult. 1, 6, and 8. By combining our own measurements withdata in the literature we assemble a sample of 253 stars in themetallicity range -3.2  [Fe/H]  +0.5. Two important features,which could hardly be detected in smaller samples, are obvious from thislarge sample: 1) a sizeable scatter in [S/Fe] ratios around [Fe/H]˜-1; 2) at low metallicities we observe stars with [S/Fe]˜ 0.4, aswell as stars with higher [S/Fe] ratios. The latter do not seem to bekinematically different from the former ones. Whether the latter findingstems from a distinct population of metal-poor stars or simply from anincreased scatter in sulphur abundances remains an open question.

Abundance trends in kinematical groups of the Milky Way's disk
We have compiled a large catalogue of metallicities and abundance ratiosfrom the literature in order to investigate abundance trends of severalalpha and iron peak elements in the thin disk and the thick disk of theGalaxy. The catalogue includes 743 stars with abundances of Fe, O, Mg,Ca, Ti, Si, Na, Ni and Al in the metallicity range -1.30 < [Fe/H]< +0.50. We have checked that systematic differences betweenabundances measured in the different studies were lower than randomerrors before combining them. Accurate distances and proper motions fromHipparcos and radial velocities from several sources have been retreivedfor 639 stars and their velocities (U, V, W) and galactic orbits havebeen computed. Ages of 322 stars have been estimated with a Bayesianmethod of isochrone fitting. Two samples kinematically representative ofthe thin and thick disks have been selected, taking into account theHercules stream which is intermediate in kinematics, but with a probabledynamical origin. Our results show that the two disks are chemicallywell separated, they overlap greatly in metallicity and both showparallel decreasing alpha elements with increasing metallicity, in theinterval -0.80 < [Fe/H] < -0.30. The Mg enhancement with respectto Fe of the thick disk is measured to be 0.14 dex. An even largerenhancement is observed for Al. The thick disk is clearly older than thethin disk with tentative evidence of an AMR over 2-3 Gyr and a hiatus instar formation before the formation of the thin disk. We do not observea vertical gradient in the metallicity of the thick disk. The Herculesstream has properties similar to that of the thin disk, with a widerrange of metallicity. Metal-rich stars assigned to the thick disk andsuper-metal-rich stars assigned to the thin disk appear as outliers inall their properties.

Lithium abundances of the local thin disc stars
Lithium abundances are presented for a sample of 181 nearby F and Gdwarfs with accurate Hipparcos parallaxes. The stars are on circularorbits about the Galactic centre and, hence, are identified as belongingto the thin disc. This sample is combined with two published surveys toprovide a catalogue of lithium abundances, metallicities ([Fe/H]),masses, and ages for 451 F-G dwarfs, almost all belonging to the thindisc. The lithium abundances are compared and contrasted with publishedlithium abundances for F and G stars in local open clusters. The fieldstars span a larger range in [Fe/H] than the clusters for which [Fe/H]~=0.0 +/- 0.2. The initial (i.e. interstellar) lithium abundance of thesolar neighbourhood, as derived from stars for which astration oflithium is believed to be unimportant, is traced from logɛ(Li) =2.2 at [Fe/H]=-1 to logɛ(Li) = 3.2 at +0.1. This form for theevolution is dependent on the assumption that astration of lithium isnegligible for the stars defining the relation. An argument is advancedthat this latter assumption may not be entirely correct, and, theevolution of lithium with [Fe/H] may be flatter than previouslysupposed. A sharp Hyades-like Li dip is not seen among the field starsand appears to be replaced by a large spread among lithium abundances ofstars more massive than the lower mass limit of the dip. Astration oflithium by stars of masses too low to participate in the Li dip isdiscussed. These stars show little to no spread in lithium abundance ata given [Fe/H] and mass.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

The [Zn/Fe] - [Fe/H] trend for disk and halo stars
Zn abundances, derived from a model atmosphere analysis of theλ6362.35 Å Zn I line, are presented for 44 thin disk, 10thick disk and 8 halo dwarf stars in the metallicity range -1.0 <[Fe/H] < +0.2. It is found that [Zn/Fe] in thin disk stars shows aslight increasing trend with decreasing metallicity reaching a value[Zn/Fe] ≃ +0.1 at [Fe/H] = -0.6. The thick disk stars in themetallicity range -0.9 < [Fe/H] < -0.6 have an average [Zn/Fe]≃ +0.15 dex, whereas five alpha-poor and Ni-poor halo stars in thesame metallicity range have [Zn/Fe] ≃ 0.0 dex. These resultsindicate that Zn is not an exact tracer of Fe as often assumed inabundance studies of damped Lyman-alpha systems (DLAs). A betterunderstanding of the nucleosynthesis of Zn is needed in order to obtainmore detailed information on the past history of star formation in DLAsfrom e.g. the observed sulphur/zinc ratio.Based on observations collected at the National AstronomicalObservatories, Xinglong, China and the European Southern Observatory, LaSilla, Chile (ESO No. 67.D-0106).

The Geneva-Copenhagen survey of the Solar neighbourhood. Ages, metallicities, and kinematic properties of ˜14 000 F and G dwarfs
We present and discuss new determinations of metallicity, rotation, age,kinematics, and Galactic orbits for a complete, magnitude-limited, andkinematically unbiased sample of 16 682 nearby F and G dwarf stars. Our˜63 000 new, accurate radial-velocity observations for nearly 13 500stars allow identification of most of the binary stars in the sampleand, together with published uvbyβ photometry, Hipparcosparallaxes, Tycho-2 proper motions, and a few earlier radial velocities,complete the kinematic information for 14 139 stars. These high-qualityvelocity data are supplemented by effective temperatures andmetallicities newly derived from recent and/or revised calibrations. Theremaining stars either lack Hipparcos data or have fast rotation. Amajor effort has been devoted to the determination of new isochrone agesfor all stars for which this is possible. Particular attention has beengiven to a realistic treatment of statistical biases and errorestimates, as standard techniques tend to underestimate these effectsand introduce spurious features in the age distributions. Our ages agreewell with those by Edvardsson et al. (\cite{edv93}), despite severalastrophysical and computational improvements since then. We demonstrate,however, how strong observational and theoretical biases cause thedistribution of the observed ages to be very different from that of thetrue age distribution of the sample. Among the many basic relations ofthe Galactic disk that can be reinvestigated from the data presentedhere, we revisit the metallicity distribution of the G dwarfs and theage-metallicity, age-velocity, and metallicity-velocity relations of theSolar neighbourhood. Our first results confirm the lack of metal-poor Gdwarfs relative to closed-box model predictions (the ``G dwarfproblem''), the existence of radial metallicity gradients in the disk,the small change in mean metallicity of the thin disk since itsformation and the substantial scatter in metallicity at all ages, andthe continuing kinematic heating of the thin disk with an efficiencyconsistent with that expected for a combination of spiral arms and giantmolecular clouds. Distinct features in the distribution of the Vcomponent of the space motion are extended in age and metallicity,corresponding to the effects of stochastic spiral waves rather thanclassical moving groups, and may complicate the identification ofthick-disk stars from kinematic criteria. More advanced analyses of thisrich material will require careful simulations of the selection criteriafor the sample and the distribution of observational errors.Based on observations made with the Danish 1.5-m telescope at ESO, LaSilla, Chile, and with the Swiss 1-m telescope at Observatoire deHaute-Provence, France.Complete Tables 1 and 2 are only available in electronic form at the CDSvia anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/418/989

Non-LTE Analysis of the Sodium Abundance of Metal-Poor Stars in the Galactic Disk and Halo
We performed an extensive non-LTE analysis of the neutral sodium linesof Na I 5683/5688, 5890/5896, 6154/6161, and 8183/8195 in disk/halostars of types F-K covering a wide metallicity range (-4 <≈[Fe/H] <≈ +0.4), using our own data as well as data collectedfrom the literature. For comparatively metal-rich disk stars (-1<≈ [Fe/H] <≈ +0.4) where the weaker 6154/6161 linesare the best abundance indicators, we confirmed [Na/Fe] ˜ 0 with an"upturn" (i.e., a shallow/broad dip around -0.5 <≈ [Fe/H]<≈ 0) as already reported in previous studies. For themetal-deficient halo stars, where the much stronger 5890/5896 or8183/8195 lines subject to considerable (negative) non-LTE correctionsamounting to 0.5 dex have to be used, our analysis suggests mildly"subsolar" [Na/Fe] values down to ˜ -0.4 (with a somewhat largescatter of ˜ ± 0.2 dex) on the average at the typical halometallicity of [Fe/H] ˜ -2, followed by a rise again to a near-solarratio of [Na/Fe] ˜ 0 at the very metal-poor regime [Fe/H] ˜ -3to -4. These results are discussed in comparison with the previousobservational studies along with the theoretical predictions from theavailable chemical evolution models.

Observational Constraints on Potassium Synthesis During the Formation of Stars of the Galactic Disk
The non-LTE potassium abundances in the atmospheres of 33 Galactic-diskstars are derived and the parameters of the atmospheres of 23 of thestars are determined. Neglecting departures from LTE results in asystematic overestimation of the potassium abundances and an increase intheir dispersion, even for differential analyses relative to the Sun.The non-LTE corrections are significant ((-0.2) (-0.6) dex) and dependon the surface gravities and effective temperatures of the stars. Themean potassium abundance for a sample of ten stars with [Fe/H]˜0.0is in agreement with the solar and meteoritic abundances (log ɛȯ(K)=5.12). As the stellar metallicity increases from [Fe/H]=(-1.0)to (0.2) dex, the [K/Fe] ratio decreases systematically from 0.3 dex to-0.1 dex. The derived dependence [K/Fe]-[Fe/H] is in agreement with theresults of published model calculations of the chemical evolution of theGalaxy. This indicates the dominance of explosive oxygen burning inmassive type II supernovae during the synthesis of potassium in theGalactic disk.

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

Abundances for metal-poor stars with accurate parallaxes. I. Basic data
We present element-to-element abundance ratios measured from highdispersion spectra for 150 field subdwarfs and early subgiants withaccurate Hipparcos parallaxes (errors <20%). For 50 stars new spectrawere obtained with the UVES on Kueyen (VLT UT2), the McDonald 2.7 mtelescope, and SARG at TNG. Additionally, literature equivalent widthswere taken from the works by Nissen & Schuster, Fulbright, andProchaska et al. to complement our data. The whole sample includes boththick disk and halo stars (and a few thin disk stars); most stars havemetallicities in the range -2<[Fe/H]<-0.6. We found our data, thatof Nissen & Schuster, and that of Prochaska to be of comparablequality; results from Fulbright scatter a bit more, but they are stillof very good quality and are extremely useful due to the large size ofhis sample. The results of the present analysis will be used inforthcoming papers to discuss the chemical properties of thedissipational collapse and accretion components of our Galaxy.Based in part on data collected at the European Southern Observatory,Chile, at the MacDonald Observatory, Texas, USA, and at the TelescopioNazionale Galileo, Canary Island, INAF,Italy-Spain.}\fnmsep\thanks{Table 1 is only available in electronic format the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) orvia\resizebox{8.8cm}{2.2mm}htpp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/404/187}

Statistical cataloging of archival data for luminosity class IV-V stars. II. The epoch 2001 [Fe/H] catalog
This paper describes the derivation of an updated statistical catalog ofmetallicities. The stars for which those metallicities apply are ofspectral types F, G, and K, and are on or near the main sequence. Theinput data for the catalog are values of [Fe/H] published before 2002February and derived from lines of weak and moderate strength. Theanalyses used to derive the data have been based on one-dimensional LTEmodel atmospheres. Initial adjustments which are applied to the datainclude corrections to a uniform temperature scale which is given in acompanion paper (see Taylor \cite{t02}). After correction, the data aresubjected to a statistical analysis. For each of 941 stars considered,the results of that analysis include a mean value of [Fe/H], an rmserror, an associated number of degrees of freedom, and one or moreidentification numbers for source papers. The catalog of these resultssupersedes an earlier version given by Taylor (\cite{t94b}).Catalog is only available in electronic form at the CDS via anonymousftp cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/398/731

Statistical cataloging of archival data for luminosity class IV-V stars. I. The epoch 2001 temperature catalog
This paper is one of a pair in which temperatures and metallicitycatalogs for class IV-V stars are considered. The temperature catalogdescribed here is derived from a calibration based on stellar angulardiameters. If published calibrations of this kind are compared by usingcolor-index transformations, temperature-dependent differences among thecalibrations are commonly found. However, such differences are minimizedif attention is restricted to calibrations based on Johnson V-K. Acalibration of this sort from Di Benedetto (\cite{dib98}) is thereforetested and adopted. That calibration is then applied to spectroscopicand photometric data, with the latter predominating. Cousins R-Iphotometry receives special attention because of its high precision andlow metallicity sensitivity. Testing of temperatures derived from thecalibration suggests that their accuracy and precision are satisfactory,though further testing will be warranted as new results appear. Thesetemperatures appear in the catalog as values of theta equiv5040/T(effective). Most of these entries are accompanied by measured orderived values of Cousins R-I. Entries are given for 951 stars.Catalog is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/398/721

On the Abundance of Potassium in Metal-Poor Stars
Based on extensive statistical-equilibrium calculations, we performed anon-LTE analysis of the K I 7699 equivalent-width data ofmetal-deficient stars for the purpose of clarifying the behavior of thephotospheric potassium abundance in disk/halo stars. While the resultingnon-LTE abundance corrections turned out to be considerably large,amounting to 0.2-0.7dex, their effect on the [K/Fe] vs. [Fe/H] relationis not very important, since these corrections do not show anysignificant dependence on the metallicity. Hence, we again confirmed theresults of previous LTE studies, that [K/Fe] shows a gradual systematicincrease toward a lowered metallicity up to [K/Fe] ~ 0.3 - 0.5 at[Fe/H]} ~ -1 to -2, such as in the case of αelements.

A Survey of Proper-Motion Stars. XVI. Orbital Solutions for 171 Single-lined Spectroscopic Binaries
We report 25,563 radial velocity measurements for 1359 single-linedstars in the Carney-Latham sample of 1464 stars selected for high propermotion. For 171 of these, we present spectroscopic orbital solutions. Wefind no obvious difference between the binary characteristics in thehalo and the disk populations. The observed frequency is the same, andthe period distributions are consistent with the hypothesis that the twosets of binaries were drawn from the same parent population. Thissuggests that metallicity in general, and radiative opacities inparticular, have little influence over the fragmentation process thatleads to short-period binaries. All the binaries with periods shorterthan 10 days have nearly circular orbits, while the binaries withperiods longer than 20 days exhibit a wide range of eccentricities and amedian value of 0.37. For the metal-poor high-velocity halo binaries inour sample, the transition from circular to eccentric orbits appears tooccur at about 20 days, supporting the conclusion that tidalcircularization on the main sequence is important for the oldestbinaries in the Galaxy. Some of the results presented here usedobservations made with the Multiple Mirror Telescope, a joint facilityof the Smithsonian Institution and the University of Arizona.

Abundances and Kinematics of Field Stars. II. Kinematics and Abundance Relationships
As an investigation of the origin of ``α-poor'' halo stars, weanalyze kinematic and abundance data for 73 intermediate-metallicitystars (-1>[Fe/H]>=-2) selected from Paper I of this series. We findevidence for a connection between the kinematics and the enhancement ofcertain element-to-iron ([X/Fe]) ratios in these stars. Statisticallysignificant correlations were found between [X/Fe] and galacticrest-frame velocities (vRF) for Na, Mg, Al, Si, Ca, and Ni,with marginally significant correlations existing for Ti and Y as well.We also find that the [X/Fe] ratios for these elements all correlatewith a similar level of significance with [Na/Fe]. Finally, we comparethe abundances of these halo stars against those of stars in nearbydwarf spheroidal (dSph) galaxies. We find significant differencesbetween the abundance ratios in the dSph stars and halo stars of similarmetallicity. From this result, it is unlikely that the halo stars in thesolar neighborhood, including even the ``α-poor'' stars, were oncemembers of disrupted dSph galaxies similar to those studied to date.

The C and N abundances in disk stars
Abundance analysis of carbon and nitrogen has been performed for asample of 90 F and G type main-sequence disk stars with a metallicityrange of -1.0 < [Fe/H] <+0.2 using the \ion{C} i and N I lines. Weconfirm a moderate carbon excess in the most metal-poor disk dwarfsfound in previous investigations. Our results suggest that carbon isenriched by superwinds of metal-rich massive stars at the beginning ofthe disk evolution, while a significant amount of carbon is contributedby low-mass stars in the late stage. The observed behavior of [N/Fe] isabout solar in the disk stars, irrespective of the metallicity. Thisresult suggests that nitrogen is produced mostly by intermediate-massstars. Based on observations carried out at National Astrono- micalObservatories (Xinglong, China).

Revised Magnesium Abundances in Galactic Halo and Disk Stars
A differential analysis of the magnesium abundances in 61 F-K dwarfs andsubgiants with metallicities -2.6<[Fe/H]<+0.2 is performed basedon published observational data. Fundamental parameters for 36 stars aredetermined: T eff from V-K and V-R; logg from HIPPARCOS parallaxes, and[Fe/H] and ξt from Fe II lines. The computations allow for non-LTEeffects in the formation of the Mg I lines. For most of the stars, thestandard errors in the Mg abundances do not exceed 0.07 dex. Themetallicity dependence of [Mg/Fe] is analyzed. Magnesium shows aconstant overabundance relative to Fe of 0.46±0.06 dex formetallicities -2.6<[Fe/H]<-0.7 Mg. The Mg overabundance decreasesabruptly to ˜+0.27 dex at [Fe/H]⋍-0.7. At highermetallicities, the Mg abundance smoothly decreases to the solar value at[Fe/H]=0.0. Halo stars with metallicities [Fe/H]<-1.0 exhibit lowerMg overabundances ( ) compared to the [Mg/Fe] values for other starswith similar [Fe/H].

Lithium abundances for 185 main-sequence stars: Galactic evolution and stellar depletion of lithium
We present a survey of lithium abundances in 185 main-sequence fieldstars with 5600 <~ Teff <~ 6600 K and -1.4 <~ [Fe/H]<~ +0.2 based on new measurements of the equivalent width of thelambda 6708 Li I line in high-resolution spectra of 130 stars and areanalysis of data for 55 stars from Lambert et al. (\cite{Lambert91}).The survey takes advantage of improved photometric and spectroscopicdeterminations of effective temperature and metallicity as well as massand age derived from Hipparcos absolute magnitudes, offering anopportunity to investigate the behaviour of Li as a function of theseparameters. An interesting result from this study is the presence of alarge gap in the log varepsilon (Li) - Teff plane, whichdistinguishes ``Li-dip'' stars like those first identified in the Hyadescluster by Boesgaard & Tripicco (\cite{Boesgaard86}) from otherstars with a much higher Li abundance. The Li-dip stars concentrate on acertain mass, which decreases with metallicity from about 1.4Msun at solar metallicity to 1.1 Msun at [Fe/H] =~-1.0. Excluding the Li-dip stars and a small group of lower mass starswith Teff < 5900 K and log varepsilon (Li) < 1.5, theremaining stars, when divided into four metallicity groups, may show acorrelation between Li abundance and stellar mass. The dispersion aroundthe log varepsilon (Li)-mass relation is about 0.2 dex below [Fe/H] =~-0.4 and 0.3 dex above this metallicity, which cannot be explained byobservational errors or differences in metallicity. Furthermore, thereis no correlation between the residuals of the log varepsilon (Li)-massrelations and stellar age, which ranges from 1.5 Gyr to about 15 Gyr.This suggests that Li depletion occurs early in stellar life and thatparameters other than stellar mass and metallicity affect the degree ofdepletion, e.g. initial rotation velocity and/or the rate of angularmomentum loss. It cannot be excluded, however, that a cosmic scatter ofthe Li abundance in the Galaxy at a given metallicity contributes to thedispersion in Li abundance. These problems make it difficult todetermine the Galactic evolution of Li from the data, but a comparisonof the upper envelope of the distribution of stars in the log varepsilon(Li) - [Fe/H] plane with recent Galactic evolutionary models by Romanoet al. (\cite{Romano99}) suggests that novae are a major source for theLi production in the Galactic disk; their occurrence seems to be theexplanation for the steep increase of Li abundance at [Fe/H] =~ -0.4.Based on observations carried out at Beijing Astronomical Observatory(Xinglong, PR China) and European Southern Observatory, La Silla, Chile.Table 1 is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/371/943 and athttp://www.edpsciences.org

Non-LTE Abundances and Consequences for the Evolution of the α-Elements in the Galaxy
Abundances of α-elements such as Ca and Mg in disk and halo starsare usually derived from equivalent width lines measured onhigh-resolution spectra and assuming local thermodynamic equilibrium(LTE). In this paper, we present non-LTE differential abundances derivedby computing the statistical equilibrium of Ca I and Mg I atoms, usinghigh-resolution equivalent widths available in the literature for 252dwarf to subgiant stars. These non-LTE abundances, combined with recentdetermination of non-LTE abundances of iron, seem to remove thedispersion of the [Ca/Fe] and [Mg/Fe] ratios in the galactic halo anddisk phases, revealing new and surprising structures. These results haveimportant consequences for chemical evolution models of the Galaxy. Inaddition, non-LTE abundance ratios for stars belonging to the M92cluster apparently have the same behavior. More high-resolutionobservations, mainly of globular clusters, are urgently needed toconfirm our results.

Abundances and Kinematics of Field Halo and Disk Stars. I. Observational Data and Abundance Analysis
We describe observations and abundance analysis of a high-resolution,high signal-to-noise ratio survey of 168 stars, most of which aremetal-poor dwarfs. We follow a self-consistent LTE analysis technique todetermine the stellar parameters and abundances, and we estimate theeffects of random and systematic uncertainties on the resultingabundances. Element-to-iron ratios are derived for key α-, odd-Z,Fe-peak, and r- and s-process elements. Effects of non-LTE on theanalysis of Fe I lines are shown to be very small on average.Spectroscopically determined surface gravities are derived that arequite close to those obtained from Hipparcos parallaxes.

Chemical composition of 90 F and G disk dwarfs
High resolution, high S/N spectra have been obtained for a sample of 90F and G main-sequence disk stars covering the metallicity range -1.0< [Fe/H] < +0.1, and have been analysed in a parallel way to thework of Edvardsson et al. (\cite{Edvardsson93a}) in order to re-inspecttheir results and to reveal new information on the chemical evolution ofthe Galactic disk. Compared to Edvardsson et al. the present studyincludes several improvements. Effective temperatures are based on theAlonso et al. (\cite{Alonso96}) calibration of color indices by theinfrared flux method and surface gravities are calculated from Hipparcosparallaxes, which also allow more accurate ages to be calculated from acomparison of M_V and T_eff with isochrones. In addition, more reliablekinematical parameters are derived from Hipparcos distances and propermotions in combination with accurate radial velocities. Finally, alarger spectral coverage, 5600 - 8800 Ä, makes it possible toimprove the abundance accuracy by studying more lines and to discussseveral elements not included in the work of Edvardsson et al. Thepresent paper provides the data and discusses some general results ofthe abundance survey. A group of stars in the metallicity range of -1.0< [Fe/H] < -0.6 having a small mean Galactocentric distance in thestellar orbits, R_m < 7 kpc, are shown to be older than the otherdisk stars and probably belong to the thick disk. Excluding these stars,a slight decreasing trend of [Fe/H] with increasing R_m and age isfound, but a large scatter in [Fe/H] (up to 0.5 dex) is present at agiven age and R_m. Abundance ratios with respect to Fe show, on theother hand, no significant scatter at a given [Fe/H] . The derivedtrends of O, Mg, Si, Ca, Ti, Ni and Ba as a function of [Fe/H] agreerather well with those of Edvardsson et al., but the overabundance of Naand Al for metal-poor stars found in their work is not confirmed.Furthermore, the Galactic evolution of elements not included inEdvardsson et al., K, V and Cr, is studied. It is concluded that theterms ``alpha elements" and ``iron-peak elements" cannot be used toindicate production and evolution by specific nucleosynthesis processes;each element seems to have a unique enrichment history. Based onobservations carried out at the Beijing Astronomical Observatory,Xinglong, PR China.}\fnmsep\thanks{ Tables~3, 4 and 5 are only availablein electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr(130.79.128.5) or via http://cdsweb.u-strasbg.fr/Abstract.htmlor\protect\\ http://www.edpsciences.org

Sc and Mn abundances in disk and metal-rich halo stars
Sc and Mn abundances are determined for 119 F and G main-sequence starswith -1.4 < [Fe/H] < +0.1, representing stars from the thin disk,the thick disk and the halo. The results indicate that Sc behaves likean alpha element, showing a decreasing [Sc/Fe] with increasingmetallicity in disk stars and a dual pattern in the kinematicallyselected halo stars. In contrast, Mn shows an increase from [Mn/Fe] =~-0.5 at [Fe/H] = -1.4 to zero at solar metallicity. There appears to bea discontinuity or sharp increase of [Mn/Fe] at [Fe/H] =~ -0.7corresponding to the transition between the thick and the thin disk. Itis discussed if supernovae of Type Ia are a major source of Mn in theGalactic disk or if the trend of [Mn/Fe] vs. [Fe/H] can be explained bynucleosynthesis in Type II supernovae with a strong metallicitydependence of the yield. Based on observations carried out at theEuropean Southern Observatory, La Silla, Chile, and Beijing AstronomicalObservatory, Xinglong, China

Chemical composition of halo and disk stars with overlapping metallicities.
High resolution (R=60000), high S/N spectra have been obtained for 13halo stars and 16 disk stars with 5400<~T_eff_<~6500K,4.0<~logg<~4.6 and overlapping metallicities in the range-1.3<~[Fe/H]<~-0.5. Equivalent widths of weak FeI and FeII linesare used to determine differential values of T_eff_ and logg. Relativeabundances of O, Na, Mg, Si, Ca, Ti, Cr, Fe, Ni, Y and Ba are determinedto a precision ranging from 0.02 to 0.07dex. Kinematical data have beencollected and used to calculate the stellar orbital parameters, R_max_,the maximum distance from the Galactic center, and z_max_, the maximumdistance from the Galactic plane. A group of 8 halo stars havesignificantly lower [α/Fe] values than disk stars of the samemetallicity (α= O, Mg, Si, Ca or Ti). These stars are alsounderabundant in Na and Ni and maybe in Cr. [Na/Fe] ranges from -0.4 to+0.1, and [Ni/Fe] is surprisingly well correlated with [Na/Fe]. Thesmallest values of [α/Fe] and [Na/Fe] are found for the stars withthe largest values of R_max_ and z_max_. This may indicate that theanomalous halo stars have been accreted from dwarf galaxies with achemical evolution history different from that of the inner halo and thedisk. In any case the data show that abundance ratios in stars are notuniversal functions of [Fe/H] and that the chemical evolution of theGalaxy at [Fe/H]=~-1.0 is more complicated than assumed in many models.One halo star, HD 106038, is found to be strongly overabundant in Si,Ni, Y and Ba relative to Fe.

A survey of proper motion stars. 12: an expanded sample
We report new photometry and radial velocities for almost 500 stars fromthe Lowell Proper Motion Catalog. We combine these results with ourprior sample and rederive stellar temperatures based on the photometry,reddening, metallicities (using chi squared matching of our 22,500 lowSignal to Noise (S/N) high resolution echelle spectra with a grid ofsynthetic spectra), distances, space motions, and Galactic orbitalparameters for 1269 (kinematics) and 1261 (metallicity) of the 1464stars in the complete survey. The frequency of spectroscopic binariesfor the metal-poor ((m/H) less than or equal to -1.2) stars with periodsshorter than 3000 days is at least 15%. The spectroscopic binaryfrequency for metal-rich stars ((m/H) greater than -0.5) appears to belower, about 9%, but this may be a selection effect. We also discussspecial classes of stars, including treatment of the double-linedspectroscopic binaries, and identification of subgiants. Four possiblenew members of the class of field blue stragglers are noted. We pointout the detection of three possible new white dwarfs, six broad-lined(binary) systems, and discuss briefly the three already knownnitrogen-rich halo dwarfs. The primary result of this paper will beavailable on CD-ROM, in the form of a much larger table.

Early type high-velocity stars in the solar neighborhood. IV - Four-color and H-beta photometry
Results are presented from photometric obaservations in the Stromgrenuvby four-color and H-beta systems of early-type high-velocity stars inthe solar neighborhood. Several types of photometrically peculiar starsare selected on the basis of their Stromgren indices and areprovisionally identified as peculiar A stars, field horizontal-branchstars, metal-poor stars near the Population II and old-disk turnoffs,metal-poor blue stragglers, or metallic-line A stars. Numerousphotometrically normal stars were also found.

Overionization of neutral iron in the atmospheres of solar-type subdwarfs
The model atmosphere method is used to perform iron abundancecomputations for 30 subdwarfs with T(eff) between 5500 and 6500 K in theFe/H range between -0.1 and -2.3. It is shown that there is a systematicdifference in the iron abundances determined from Fe I and Fe II lines.This difference increases with decreasing metallicity. Non-LTEcomputations of the Fe I-Fe II ionization balance are performed usingobserved UV fluxes. It is found that, in the atmospheres of subdwarfs,an overionization of neutral iron atoms occurs, leading to a weakeningof Fe I line intensity and to the systematic underestimation of theabundances. It is concluded that the Fe II lines must be used forcorrect determinations of iron abundance in the atmospheres of subdwarfssince they are not sensitive to the effect of the overionization of FeI.

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